Cause of the fragile-to-strong transition observed in water confined in C-S-H gel

In this study, the rotational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel with a water content of 22 wt.% was studied by broadband dielectric spectroscopy in broad temperature (110-300 K) and frequency (10(-1)-10(8) Hz) ranges. The C-S-H gel was used as a 3D confining system for investigating the possible existence of a fragile-to-strong transition for water around 220 K. Such transition was observed at 220 K in a previous study [Y. Zhang, M. Lagi, F. Ridi, E. Fratini, P. Baglioni, E. Mamontov and S. H. Chen, J. Phys.: Condens. Matter 20, 502101 (2008)] on a similar system, and it was there associated with a hidden critical point of bulk water. However, based on the experimental results presented here, there is no sign of a fragile-to-strong transition for water confined in C-S-H gel. Instead, the fragile-to-strong transition can be explained by a merging of two different relaxation processes at about 220 K. (C) 2013 AIP Publishing LLC

Values Mapping and Counter-Mapping in Contested Landscapes: an Olympic Peninsula (USA) Case Study

Indigenous peoples, local communities, and other groups can use counter-mapping to make land claims, identify areas of desired access, or convey cultural values that diverge from the dominant paradigm. While sometimes created independently, counter-maps also can be formulated during public participation mapping events sponsored by natural resource planning agencies. Public participation mapping elicits values, uses, and meanings of landscapes from diverse stakeholders, yet individuals and advocacy groups can use the mapping process as an opportunity to make visible strongly held values and viewpoints. We present three cases from the Olympic Peninsula in Washington State to illustrate how stakeholders intentionally used landscape-values mapping workshops to amplify their perspectives in attempts to further political outcomes. We combine geospatial analysis with qualitative data to explore ways that landscape-values mapping were used as a political tool and how social scientists engaged in similar efforts can defend the scientific integrity of results

Multiple Methods of Public Engagement: Disaggregating Socio-spatial Data for Environmental Planning in Western Washington, USA

Highlights • The effectiveness of participatory GIS approaches at engaging different publics was explored. • Online surveys engaged urbanites; community workshops engaged rural residents. • Urban and rural residents went to similar places but engaged in different activities. • Use of multiple data collection methods will broaden public engagement. • Mapping behavior studies are needed to improve understandings of PPGIS data quality

Modeling information technology impacts in clerical work environments

The industrialization of white collar work via information technology (IT) is a key indicator of the emerging post-industrial economy (Hirschhorn, 1988). A conceptual model linking clerical work environments to effective IT impacts such as IT utilization, IT\u27s perceived ease of use and performance impact was developed and empirically tested. Underlying the model is the premise that clerical job structure is a facilitator of IT impacts (Weber, 1988). The results indicate that clerical job structure factors such as typing, composing or editing, and bookkeeping were significantly related to IT impacts in clerical work settings. A job holder\u27s IT competence and top management commitment to IT were also found to be significantly related to IT impacts in clerical work settings. Antecedent relationships among the IT impacts also contributed to understanding the IT impacts - for example, IT utilization affected perceived ease of use and perceived performance impact, and perceived ease of use affected perceived performance impact

Effect of hydration on the dielectric properties of C-S-H gel

9 páginas, 7 figuras, 1 tabla.-- Trabajo presentado a la "Gordon Research Conference: Water & Aqueous Solutions" celebrada en EE.UU. del 8 al 13 de agosto de 2010.The behavior of water dynamics confined in hydrated calcium silicate hydrate (C-S-H) gel has been investigated using broadband dielectric spectroscopy (BDS; 10−2–106 Hz) in the low-temperature range (110–250 K). Different water contents in C-S-H gel were explored (from 6 to 15 wt%) where water remains amorphous for all the studied temperatures. Three relaxation processes were found by BDS (labeled 1 to 3 from the fastest to the slowest), two of them reported here for the first time. We show that a strong change in the dielectric relaxation of C-S-H gel occurs with increasing hydration, especially at a hydration level in which a monolayer of water around the basic units of cement materials is predicted by different structural models. Below this hydration level both processes 2 and 3 have an Arrhenius temperature dependence. However, at higher hydration level, a non-Arrhenius behavior temperature dependence for process 3 over the whole accessible temperature range and, a crossover from low-temperature Arrhenius to high-temperature non-Arrhenius behavior for process 2 are observed. Characteristics of these processes will be discussed in this work.Authors gratefully acknowledge the support of Consolider (CSD2006-00053) and Etortek program. S.C. gratefully acknowledge the support of CSIC (200860I021) and S.C. S.A-I, A.A and J.C. gratefully acknowledge the support of the DYNACOP program and the Basque Government, and project IT-436-07 and the Spanish Ministry of Education, project MAT-22007-63681.Peer reviewe

Effect of hydration on the dielectric properties of C-S-H gel

9 páginas, 7 figuras, 1 tabla.-- Trabajo presentado a la "Gordon Research Conference: Water & Aqueous Solutions" celebrada en EE.UU. del 8 al 13 de agosto de 2010.The behavior of water dynamics confined in hydrated calcium silicate hydrate (C-S-H) gel has been investigated using broadband dielectric spectroscopy (BDS; 10−2–106 Hz) in the low-temperature range (110–250 K). Different water contents in C-S-H gel were explored (from 6 to 15 wt%) where water remains amorphous for all the studied temperatures. Three relaxation processes were found by BDS (labeled 1 to 3 from the fastest to the slowest), two of them reported here for the first time. We show that a strong change in the dielectric relaxation of C-S-H gel occurs with increasing hydration, especially at a hydration level in which a monolayer of water around the basic units of cement materials is predicted by different structural models. Below this hydration level both processes 2 and 3 have an Arrhenius temperature dependence. However, at higher hydration level, a non-Arrhenius behavior temperature dependence for process 3 over the whole accessible temperature range and, a crossover from low-temperature Arrhenius to high-temperature non-Arrhenius behavior for process 2 are observed. Characteristics of these processes will be discussed in this work.Authors gratefully acknowledge the support of Consolider (CSD2006-00053) and Etortek program. S.C. gratefully acknowledge the support of CSIC (200860I021) and S.C. S.A-I, A.A and J.C. gratefully acknowledge the support of the DYNACOP program and the Basque Government, and project IT-436-07 and the Spanish Ministry of Education, project MAT-22007-63681.Peer reviewe

Solving the stationary Liouville equation via a boundary element method

Intensity distributions of linear wave fields are, in the high frequency limit, often approximated in terms of flow or transport equations in phase space. Common techniques for solving the flow equations for both time dependent and stationary problems are ray tracing or level set methods. In the context of predicting the vibro-acoustic response of complex engineering structures, reduced ray tracing methods such as Statistical Energy Analysis or variants thereof have found widespread applications. Starting directly from the stationary Liouville equation, we develop a boundary element method for solving the transport equations for complex multi-component structures. The method, which is an improved version of the Dynamical Energy Analysis technique introduced recently by the authors, interpolates between standard statistical energy analysis and full ray tracing, containing both of these methods as limiting cases. We demonstrate that the method can be used to efficiently deal with complex large scale problems giving good approximations of the energy distribution when compared to exact solutions of the underlying wave equation

Ray and wave scattering in smoothly curved thin shell cylindrical ridges

We propose wave and ray approaches for modelling mid- and high- frequency structural vibrations through smoothed joints on thin shell cylindrical ridges. The models both emerge from a simplified classical shell theory setting. The ray model is analysed via an appropriate phase-plane analysis, from which the fixed points can be interpreted in terms of the reflection and transmission properties. The corresponding full wave scattering model is studied using the finite difference method to investigate the scattering properties of an incident plane wave. Through both models we uncover the scattering properties of smoothed joints in the interesting mid-frequency region close to the ring frequency, where there is a qualitative change in the dynamics from anisotropic to simple geodesic propagation

Abrogation of Stem Loop Binding Protein (Slbp) function leads to a failure of cells to transition from proliferation to differentiation, retinal coloboma and midline axon guidance deficits

Through forward genetic screening for mutations affecting visual system development, we identified prominent coloboma and cell-autonomous retinal neuron differentiation, lamination and retinal axon projection defects in eisspalte (ele) mutant zebrafish. Additional axonal deficits were present, most notably at midline axon commissures. Genetic mapping and cloning of the ele mutation showed that the affected gene is slbp, which encodes a conserved RNA stem-loop binding protein involved in replication dependent histone mRNA metabolism. Cells throughout the central nervous system remained in the cell cycle in ele mutant embryos at stages when, and locations where, post-mitotic cells have differentiated in wild-type siblings. Indeed, RNAseq analysis showed down-regulation of many genes associated with neuronal differentiation. This was coincident with changes in the levels and spatial localisation of expression of various genes implicated, for instance, in axon guidance, that likely underlie specific ele phenotypes. These results suggest that many of the cell and tissue specific phenotypes in ele mutant embryos are secondary to altered expression of modules of developmental regulatory genes that characterise, or promote transitions in, cell state and require the correct function of Slbp-dependent histone and chromatin regulatory genes